Mechanisms of Atmospheric Oxidation of the Alkanes pdf epub mobi txt 电子书下载 2026

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出版者:

作者:Calvert, Jack G./ Derwent, Richard G./ Orlando, John J./ Tyndall, Geoffrey S./ Wallington, Timothy J

出品人:

页数:1004

译者:

出版时间:2008-9

价格:$ 141.25

装帧:

isbn号码:9780195365818

丛书系列:

图书标签:

大气化学
烷烃氧化
自由基化学
大气氧化机制
环境化学
有机大气化学
反应动力学
大气污染
羟基自由基
臭氧层

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具体描述

An international team of eminent atmospheric scientists have prepared Mechanisms of Atmospheric Oxidation of the Alkanes as an authoritative source of information on the role of alkanes in the chemistry of the atmosphere. The book includes the properties of the alkanes and haloalkanes, as well as a comprehensive review and evaluation of the existing literature on the atmospheric chemistry of the alkanes and their major atmospheric oxidation products, and the various approaches now used to model the alkane atmospheric chemistry. Comprehensive coverage is given of both the unsubstituted alkanes and the many haloalkanes. All the existing quality measurements of the rate coefficients for the reactions of OH, Cl, O(3P), NO3, and O3 with the alkanes, the haloalkanes, and their major oxidation products have been reviewed and evaluated. The expert authors then give recommendations of the most reliable kinetic data. They also review the extensive literature on the mechanisms and rates and modes of photodecomposition of the haloalkanes and the products of atmospheric oxidation of the alkanes and the haloalkanes, and make recommendations for future use by atmospheric scientists.The evaluations presented allow an extrapolation of the existing kinetic and photochemical data to those alkanes and haloalkanes that are as yet unstudied. The current book should be of special interest and value to the modelers of atmospheric chemistry as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the alkanes, their major oxidation products, and their influence on ozone and other trace gases within the troposphere.

这本书旨在深入探讨天然气等烷烃在大气环境中的化学反应过程，其核心逻辑围绕着气体在阳光、温度和压力变化下发生氧化反应的机制展开。书中系统梳理了不同条件下烷烃与大气成分如氮氧化物、臭氧等物质相互作用的详细原理，通过理论模型和实验数据揭示这些过程在地球大气层中的重要性。读者将能够全面理解烷烃如何通过光化学反应生成二次污染物，尤其是对空气质量及环境保护产生深远影响的科学内涵。内容设计紧扣基础化学知识和实际应用，内容覆盖了从分子结构、光化学反应路径到氧化产物分布的各个方面。作者特别注重对读者的引导，力求帮助他们掌握烷烃在大气环境中的复杂行为模式，并结合具体案例分析其对生态系统和人类健康的潜在影响。书中还详细描述了现代观测技术与实验方法的发展，使得研究者能够更准确地捕捉这些反应过程的细微变化。图文并茂的结构设计使得复杂概念更加直观，例如通过图示展示不同温度条件下烷烃氧化反应的动态变化，或通过数据表格对各类污染物生成路径进行解析。这些细节不仅提升了学习效果，也帮助读者建立清晰的认知框架。书中还特别强调环境科学与化学原理的结合，通过案例分析展示理论在实际研究中的应用价值。总体来说，这本书以严谨的科学论述和丰富的实证资料为核心，帮助读者深入理解烷烃大气氧化过程的多重机制，并为相关领域的研究提供有力支持。其内容不仅具有教育意义，更具备一定的实践指导作用，适合对环境化学、污染物生成及气候变化研究感兴趣的学习者。通过详细解析这一科学问题，读者将获得更全面的认知和分析能力。