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Hyperspherical Harmonics and Generalized Sturmians (Progress in Theoretical Chemistry and Physics) 在线电子书 pdf 下载 txt下载 epub 下载 mobi 下载 2024

Hyperspherical Harmonics and Generalized Sturmians (Progress in Theoretical Chemistry and Physics)
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简体网页||繁体网页
John S. Avery 作者
Springer
译者
1999-11-30 出版日期
204 页数
USD 123.00 价格
Hardcover
丛书系列
9780792360872 图书编码

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Hyperspherical Harmonics and Generalized Sturmians (Progress in Theoretical Chemistry and Physics) 在线电子书 pdf 下载 txt下载 epub 下载 mobi 下载 2024


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Hyperspherical Harmonics and Generalized Sturmians (Progress in Theoretical Chemistry and Physics) 在线电子书 图书描述

This book explores the connections between the theory of hyperspherical harmonics, momentum-space quantum theory, and generalized Sturmian basis functions; and it introduces methods which may be used to solve many-particle problems directly, without the use of the self-consistent-field approximation. The method of many-electron Sturmians offers an interesting and fresh alternative to the usual SCF-CI methods for calculating atomic and molecular structure. When many-electron Sturmians are used, and when the basis potential is chosen to be the attractive potential of the nuclei in the system, the following advantages are offered: the matrix representation of the nuclear attraction potential is diagonal; the kinetic energy term vanishes from the secular equation; the Slater exponents of the atomic orbitals are automatically optimized; convergence is rapid; a correlated solution to the many-electron problem can be obtained directly, without the use of the SCF approximation; and excited states can be obtained with good accuracy.

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