Alkene Polymerization Reactions with Transition Metal Catalysts, Volume 173 在线电子书 pdf 下载 txt下载 epub 下载 mobi 下载 2024


Alkene Polymerization Reactions with Transition Metal Catalysts, Volume 173

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Kissin, Yury 作者
译者
2008-3 出版日期
495 页数
1963.00元 价格
丛书系列
9780444532152 图书编码

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Alkene Polymerization Reactions with Transition Metal Catalysts, Volume 173 在线电子书 epub 下载 mobi 下载 pdf 下载 txt 下载 2024

Alkene Polymerization Reactions with Transition Metal Catalysts, Volume 173 在线电子书 epub 下载 mobi 下载 pdf 下载 txt 下载 2024

Alkene Polymerization Reactions with Transition Metal Catalysts, Volume 173 在线电子书 pdf 下载 txt下载 epub 下载 mobi 下载 2024



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Alkene Polymerization Reactions with Transition Metal Catalysts, Volume 173 在线电子书 著者简介

Yury Kissin (born in 1937) received his degree in Polymer Chemistry in 1965 at Institute of Chemical Physics in Moscow investigating α-olefin polymerization reactions with heterogeneous Ziegler-Natta catalysts. Since 1960 until 1977 he worked in Institute of Chemical Physics studying kinetics of polymerization reactions of ethylene, propylene and higher α-olefins and the structure of polyolefins and catalysts by IR. He immigrated to USA in 1979 and worked as Research Associate first at Gulf Research and Development Company in Pittsburgh, PA (1980-1985), at Edison Research Center of Mobil Chemical Company in NJ (1985-2000), and at Engelhard/BASF Research Center in Iselin, NJ (2004-2008). His main research subjects were synthesis of Ziegler-Natta catalysts, kinetics of polymerization and oligomerization reactions, and spectroscopic studies of polymerization catalysts. Since 2000 he is a Visiting Scientist at Department of Chemistry of Rutgers University, NJ, where he studies kinetics of olefin polymerization reactions with Ziegler-Natta and late-period transition metal catalysts. He authored three books (Isospecific Polymerization of Olefins, Springer, 1985; Polymers and Copolymers of Higher α-Olefins, Hanser, 1997; Alkene Polymerization Reactions with Transition Metal Catalysts, Elsevier, 2008), twenty articles in chemical and polymer encyclopedias, ~210 scientific articles, and over 60 patents in the fields of synthesis of Ziegler-Natta and metallocene catalysts.


Alkene Polymerization Reactions with Transition Metal Catalysts, Volume 173 在线电子书 图书目录


Alkene Polymerization Reactions with Transition Metal Catalysts, Volume 173 在线电子书 pdf 下载 txt下载 epub 下载 mobi 在线电子书下载

Alkene Polymerization Reactions with Transition Metal Catalysts, Volume 173 在线电子书 图书描述

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes:

1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure.

2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands.

3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts.

4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers.

These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins.

The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms.

The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene

The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts.

The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism.

The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers

The book contains over 2000 references, the most recent up to end of 2006.

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