The Nature of the Hydrogen Bond 在線電子書 pdf 下載 txt下載 epub 下載 mobi 下載 2024

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Gastone Gilli 作者

Oxford University Press, USA

譯者

2009-8-25 出版日期

304 頁數

USD 130.00 價格

Hardcover

叢書系列

9780199558964 圖書編碼

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The Nature of the Hydrogen Bond 在線電子書 epub 下載 mobi 下載 pdf 下載 txt 下載 2024

The Nature of the Hydrogen Bond 在線電子書 epub 下載 pdf 下載 mobi 下載 txt 下載 2024

The Nature of the Hydrogen Bond 在線電子書 pdf 下載 txt下載 epub 下載 mobi 下載 2024

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The Nature of the Hydrogen Bond 在線電子書 pdf 下載 txt下載 epub 下載 mobi 在線電子書下載

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Hydrogen bond (H-bond) effects are known: it makes sea water liquid, joins cellulose microfibrils in trees, shapes DNA into genes and polypeptide chains into wool, hair, muscles or enzymes. Its true nature is less known and we may still wonder why O-H...O bond energies range from less than 1 to more than 30 kcal/mol without apparent reason. This H-bond puzzle is re-examined here from its very beginning and presented as an inclusive compilation of experimental H-bond energies and geometries. New concepts emerge from this analysis: new classes of systematically strong H-bonds (CAHBs and RAHBs: charge- and resonance-assisted H-bonds); full H-bond classification in six classes (the six chemical leitmotifs); and assessment of the covalent nature of strong H-bonds. This leads to three distinct but inter-consistent models able to rationalize the H-bond and predict its strength, based on classical VB theory, matching of donor-acceptor acid-base parameters (PA or pKa), or shape of the H-bond proton-transfer pathway. Applications survey a number of systems where strong H-bonds play an important functional role, namely drug-receptor binding, enzymatic catalysis, ion-transport through cell membranes, crystal design and molecular mechanisms of functional materials.

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