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Stephen Z.D. Cheng 作者

译者

2008-8 出版日期

324 页数

1351.00 价格

丛书系列

9780444519115 图书编码

Phase Transitions in Polymers 在线电子书图书标签: 物理

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发表于2024-11-21

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Phase Transitions in Polymers 在线电子书 epub 下载 mobi 下载 pdf 下载 txt 下载 2024

Phase Transitions in Polymers 在线电子书 pdf 下载 txt下载 epub 下载 mobi 下载 2024

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A classical metastable state possesses a local free energy minimum at infinite sizes, but not a global one. This concept is phase size independent. We have studied a number of experimental results and proposed a new concept that there exists a wide range of metastable states in polymers on different length scales where their metastability is critically determined by the phase size and dimensionality. Metastable states are also observed in phase transformations that are kinetically impeded on the pathway to thermodynamic equilibrium. This was illustrated in structural and morphological investigations of crystallization and mesophase transitions, liquid-liquid phase separation, vitrification and gel formation, as well as combinations of these transformation processes. The phase behaviours in polymers are thus dominated by interlinks of metastable states on different length scales. This concept successfully explains many experimental observations and provides a new way to connect different aspects of polymer physics.

* Written by a leading scholar and industry expert * Presents new and cutting edge material encouraging innovation and future research * Connects hot topics and leading research in one concise volume

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