Preface to the Third Edition
Preface to the Second Edition
Preface to the First Edition
PART ONE THE FORCES BETWEEN ATOMS AND MOLECULES
1．Historical Perspective
1．1．The Four Forces of Nature
1．2．Greek and Medieval Notions of Intermolecular Forces
1．3．The Seventeenth Century：First Scientific Period
1．4．The Eighteenth Century：Confusion，Contradictions，and Controversy
1．5．The Nineteenth Century：Continuum versus Molecular Theories
1．6．Intermolecular Force—Laws and Interaction Potentials：Long— and Short—Range Forces
1．7．First Successful Phenomenololgical Theories
1．8．First Estimates of Molecular Sizes
1．9．The Twentieth Century：Understanding Simple Systems
1．10．Recent Trends
Problems and Discussion Topics
2．Thermodynamic and Statistical Aspects of Intermolecular Forces
2．1．The Interaction of Molecules in Free Space and in a Medium
2．2．Self—Energy and Pair Potential
2．3．The Boltzmann Distribution and the Chemical Potential
2．4．The Distribution of Molecules and Particles in Systems at Equilibrium
2．5．The Van der waals Equation of State（EOS）
2．6．The Criterion of the Thermal Energy kT for Gauging the Strength of an Interaction
2．7．Classification of Forces and Pair Potentials
2．8．Theoretical Analyses of Multimolecular Systems：Continuum and Molecular Approaches
2．9．Molecular Approaches via Computer Simulations：Monte Carlo（MC）and Molecular Dynamics（MD）
2．10．Newton’s Laws Applied to Two—Body Collisions
2．11．Kinetic and Statistical Aspects of Multiple Collisions：the Boltzmann Distribution
Problems and Discussion Topics
3．Strong Intermolecular Forces：Covalent and Coulomb Interactions
3．1．Covalent or Chemical Bonding Forces
3．2．Physical and Chemical Bonds
3．3．Coulomb Forces or Charge—Charge Interactions．Gauss’s Law
3．4．Ionic Crystals
3．5．Reference States
3．6．Range of Electrostatic Forces
3．7．The Born Energy of an Ion
3．8．Solubility of Ions in Different Solvents
3．9．Specific Ion—Solvent Effects：Continuum Approach
3．10．Molecular Approach：Computer Simulations and Integral Equations of Many—Body Systems
Problems and Discussion Topics
4．Interactions Involving Polar Molecules
4．1．What Are Polar Molecules？
4．2．Dipole Self—Energy
4．3．Ion—Dipole Interactions
4．4．Ions in Polar Solvents
4．5．Strong Ion—Dipole Interactions in Water：Hydrated Ions
4．6．Solvation Forces，Structural Forces，and Hydration Forces
4．7．Dipole—Dipole Interactions
4．8．Magnetic Dipoles
4．9．Hydrogen Bonds
4．10．Rotating Dipoles and Angle—Averaged Potentials
4．11．Entropic Efiects
Problems and Discussion Topics
5．Interactions Involving the Polarization of Molecules
5．1．The Polarizability of Atoms and Molecules
5．2．The Polarizability of Polar Molecules
5．3．Other Polarization Mechanisms and the Efiects of Polarization on Electrostatic Interactions
5．4．Interactions between Ions and Uncharged Moleculas
5．5．Ion—Solvent Molecule Interactions and the Born Energy
5．6．Dipole—Induced Dipole Interactions
5．7．Unification of Polarization Interactions
5．8．Solvent Effects and“Excess Polarizabilities” Problems and Discussion Topics
6．Van der Waals Forces
6．1．Origin of the Van der Waals—dispersion Force between Neutral Molecules：the London Equation
6．2．Strength of Dispersion Forces：Van der Waals Solids and Liquids
6．3．Van der Waals Equation of State
6．4．Gas—Liquid and Liquid—Solid Phase Transitions in 3D and 2D
6．5．Van der Waals Forces between Polar Molecules
6．6．General Theory of Van der Waals Forces between Molecules
6．7．Van der Waals Forces in a Medium
6．8．Dispersion Self—Energy of a Molecule in a Medium
6．9．Further Aspects of Van der Waals Forces：Anisotropy（Orientation），Nonadditivity（Many—Body），and Retardation Effects
Problems and Discussion Topics
7．Repulsive Steric Forces，Total Intermolecular Pair Potentials，and Liquid Structure
7．1．Sizes of Atoms，Molecules，and Ions
7．2．Repulsive Potentials
7．3．Total Intermolecular Pair Potentials：Their Form，Magnitude，and Range
7．4．Role of Repulsive Forces in Noncovalenfly Bonded Solids
7．5．Packing of Molecules and Particles in Solids
7．6．Role of Repulsive Forces in Liquids：Liquid Structure
7．7．The EffeCt of Liquid Structure on Molecular Forces
Problems and Discussion Topics
8．Special Interactions：Hydrogen—Bonding and Hydrophobic and Hydrophilic Interactions
8．1．The Unique Properties of water
8．2．The Hydrogen Bond
8．3．Models of Water and Associated Liquids
8．4．Relative Strengths of Different Types of Interactions
8．5．The Hydrophobic Effect
8．6．The Hydrophobic Interaction
8．7．Hydrophilic Interactions
Problems and Discussion Topics
9．Nonequilibrium and Time．Dependent Interactions
9．1．Time— and Rate—Dependent Interactions and Processes
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PART TWO THE FORCES BETWEEN PARTICLES AND SURFACES
PART THREE SELF—ASSEMBLING STRUCTURES AND BIOLOGICAL SYSTEMS
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